Photoelectrocatalytic Reduction of CO2 into Chemicals Using Pt-Modified Reduced Graphene Oxide Combined with Pt-Modified TiO2 Nanotubes
Citations Over TimeTop 10% of 2014 papers
Abstract
The photoelectrocatalytic (PEC) reduction of CO2 into high-value chemicals is beneficial in alleviating global warming and advancing a low-carbon economy. In this work, Pt-modified reduced graphene oxide (Pt-RGO) and Pt-modified TiO2 nanotubes (Pt-TNT) were combined as cathode and photoanode catalysts, respectively, to form a PEC reactor for converting CO2 into valuable chemicals. XRD, XPS, TEM, AFM, and SEM were employed to characterize the microstructures of the Pt-RGO and Pt-TNT catalysts. Reduction products, such as C2H5OH and CH3COOH, were obtained from CO2 under band gap illumination and biased voltage. A combined liquid product generation rate (CH3OH, C2H5OH, HCOOH, and CH3COOH) of approximately 600 nmol/(h·cm(2)) was observed. Carbon atom conversion rate reached 1,130 nmol/(h·cm(2)), which were much higher than those achieved using Pt-modified carbon nanotubes and platinum carbon as cathode catalysts.
Related Papers
- → Statistical Raman Microscopy and Atomic Force Microscopy on Heterogeneous Graphene Obtained after Reduction of Graphene Oxide(2014)112 cited
- → Orthotropic friction at the edges and interior of graphene and graphene fluoride and frictional anisotropy of graphene at the nanoscale(2021)1 cited
- A natural advantage? Using mined graphite to make graphene(2013)
- Synthesis and Characterisation of Graphene Single Sheets(2012)
- Unique synthesis of graphene-based materials for clean energy and biological sensing applications(2012)