One-Dimensional Assemblies of Dirhodium Units Bridged by N,N‘-Dicyanoquinonediimine Ligands
Inorganic Chemistry2000Vol. 39(25), pp. 5870–5873
Citations Over TimeTop 14% of 2000 papers
Abstract
Two new 1-D compounds of Rh2(O2CCF3)4 bridged by dicyano linkers were synthesized and structurally characterized. [Rh2(O2CCF3)4(DM-DCNQI)]∞·(C6H6) (1) and [Rh2(O2CCF3)4(DCNNQI)]∞·(C7H8) (2) (DM-DCNQI = 2,5-dimethyl-N,N‘-dicyanoquinone diimine, DCNNQI = N,N‘-dicyanonaphthaquinone diimine) exhibit different chain motifs because of anti versus syn N−C⋮N linkages.
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