Synthesis and Structural Characterization of Zn(O3PCH2OH), a New Microporous Zinc Phosphonate
Inorganic Chemistry2001Vol. 40(7), pp. 1477–1481
Citations Over TimeTop 10% of 2001 papers
Abstract
Zn(O3PCH2OH) (1) has been formed by reaction of zinc acetate with diethyl hydroxymethylphosphonate. The acidity of the zinc solution effects hydrolysis of the phosphonate to produce phosphonic acid in situ. 1 crystallizes in the trigonal spacegroup R3̄, with a = 15.9701(2) Å, c = 7.783(2) Å, and Z = 18. The compound has channels in the [001] direction, formed by phosphonate groups bridging the octahedral coordinated zinc atoms. The zinc atoms are coordinated by the three oxygens of the phosphonate group and the oxygen of the hydroxy group.
Related Papers
- → Preparation of a novel series of phosphonate norstatine renin inhibitors(1994)34 cited
- → Synthesis and structures of a pentanuclear Al(iii) phosphonate cage, an In(iii) phosphonate polymer, and coordination compounds of the corresponding phosphonate ester with GaI3 and InCl3(2012)12 cited
- → Facile installation of the phosphonate and (α,α-difluoromethyl)phosphonate functionalities equipped with benzyl protection(1999)37 cited
- → Concerning the angular dependence of the Vicinal31P1H coupling constants of phosphonate and of hydroxy‐phosphonate derivatives(1973)20 cited
- → Effect of the phosphonate group on the reactivity of carbenes. Neighbouring phosphonate group participation(1989)14 cited