Kinetics of the Oxidation of Triphenylphosphine by Nitric Oxide
Inorganic Chemistry2002Vol. 41(4), pp. 1026–1028
Citations Over Time
Abstract
The oxidation of PPh3 by NO to N2O and Ph3PO in homogeneous solution occurs by third-order kinetics, d[Ph3P]/dt = k3[Ph3P][NO]2; analysis of solvent and substituent effects suggests formation of a phosphonium diazeniumdiolate intermediate prior to oxygen transfer from nitrogen to phosphorus.
Related Papers
- → Electroreduction of Triphenylphosphine Oxide to Triphenylphosphine in the Presence of Chlorotrimethylsilane(2011)15 cited
- → A Practical One-Pot Transformation of Triphenylphosphine Oxide to Triphenylphosphine by Reduction of in situ Generated Triphenylphosphine Dichloride(2010)9 cited
- → Syntheses and catalytic properties of iron triphenylphosphine oxide complexes(1991)3 cited
- INTERACTION OF MOLECULAR-OXYGEN WITH BIS(TRIPHENYLPHOSPHINE)-DICHLORO AND BIS(TRIPHENYLPHOSPHINE OXIDE)-DICHLORO IRON(II) - SYNTHESIS AND SPECTRAL CHARACTERIZATION OF NEW BRIDGED IRON(III) DERIVATIVES(1986)
- → Synthesis of hydroxyphosphoranes from triphenylphosphine and triphenylphosphine oxide(1993)1 cited