Unique 2:1 Complex with a trans-Chelating Bis-Pyridine Ligand
Inorganic Chemistry2002Vol. 41(8), pp. 2296–2300
Citations Over TimeTop 14% of 2002 papers
Abstract
The trans-chelating ligand 1,2-bis(2'-pyridylethynyl)benzene (1) was prepared in a single step by a Sonogashira cross-coupling reaction. Treatment of 1 with trans-bis(acetonitrile)palladium chloride provides the complex [Pd(1)Cl2] while treatment with tetrakis(acetonitrile)palladium(II) tetrafluoroborate provides the 2:1 complex [Pd(1)2](BF4]2. The structural, spectroscopic, and thermal properties of 1 and its Pd(II) complexes are examined.
Related Papers
- → THE VIBRATIONAL SPECTRA OF PYRIDINE, PYRIDINE-4-d, PYRIDINE-2,6-d2, AND PYRIDINE-3,5-d2(1957)146 cited
- → Adsorption of pyridine onto the metal organic framework MIL-101(2011)37 cited
- → Water soluble σ-bonded organochromium compounds; unsubstit utedand substituted dichlorotris(pyridine)benzylchromium(III) complexes(1966)17 cited
- → Craig 2‐Bromo‐Pyridine Synthesis(2010)
- → ИСПОЛЬЗОВAНИЕ ПОТЕНЦИAЛA СОЦИAЛЬНЫХ ПAРТНЕРОВ В ПОДГОТОВКЕ БУДУЩИХ ПЕДAГОГОВ(2024)