A Monomeric Imidazol-2-ylidene−Silver(I) Chloride Complex: Synthesis, Structure, and Solid State 109Ag and 13C CP/MAS NMR Characterization
Inorganic Chemistry2003Vol. 42(5), pp. 1391–1393
Citations Over TimeTop 10% of 2003 papers
Abstract
The structure of 1,3-bis(2,4,6-trimethylphenyl)-imidazol-2-ylidene-silver(I) chloride, 1, has been determined to be a monomer with weak head-to-tail H...Cl interactions in the solid state. A multinuclear NMR study using a (13)C(carbene) labeled derivative, 1((13)C), exhibits (13)C-(107,109)Ag coupling in solution. Further, the solid state CP/MAS NMR parameters, including the principal components of the chemical shift tensors for both the (13)C and (109)Ag centers, have been determined. With the aid of DFT calculations, the orientation of the chemical shift tensors have been assigned.
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