Unprecedented Low Cu−N(azide)−Cu Angles in End-On Double Azido Bridged Copper(II) Complex
Inorganic Chemistry2004Vol. 43(3), pp. 840–842
Citations Over TimeTop 10% of 2004 papers
Abstract
A rare asymmetric end-on double azido-bridged copper(II) complex has been synthesized and characterized structurally and magnetically. The Cu-N(azide)-Cu angle in this complex is calculated to be 89.1 degrees. This is unusually low in comparison to the same angle in other end-on azido-bridged binuclear complexes reported so far. Though a strong ferromagnetic interaction between the metal centers is expected in the complex, the coupling has actually been found to be antiferromagnetic, instead.
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