One-Dimensional Chain of Tetranuclear Manganese Single-Molecule Magnets
Inorganic Chemistry2005Vol. 44(10), pp. 3377–3379
Citations Over TimeTop 10% of 2005 papers
Jae Soo Yoo, Wolfgang Wernsdorfer, En‐Che Yang, Motohiro Nakano, Arnold L. Rheingold, David N. Hendrickson
Abstract
A one-dimensional chain of interconnected single-molecule magnets (SMMs) is obtained that consists of [Mn(4)(hmp)(6)](4+) units bridged by chloride ions. Slow magnetization relaxation is evident in the AC susceptibility data and in magnetization hysteresis measurements for [Mn(4)(hmp)(6)Cl(2)](n)(ClO(4))(2)(n). The magnetization hysteresis loops for this complex are similar to those for an SMM and show significant coercive field and steps at regular magnetic intervals. Spin-canted antiferromagnetic coupling due to misalignment of easy axes of neighboring Mn(4) units is also observed for this complex.
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