Ditopic Double Pincer Palladacycle Catalyst for C−C Coupling
Inorganic Chemistry2004Vol. 43(23), pp. 7275–7277
Citations Over TimeTop 14% of 2004 papers
Abstract
A ditopic palladacycle with SCS pincer coordination, L(PdCl)(2) (1), was isolated and structurally characterized and represents the first example of a transition metal complex with a polythioamide-based macrocycle. Preliminary studies of 1 in the catalytic coupling of 4-iodotoluene and styrene indicated it to be robust in the presence of oxygen and high temperatures, with high turnover numbers in relatively short times.
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