[CoAu2(CN)4(NITpPy)2(H2O)2]n: A New 2-D Interdigitating Complex Containing Dicyanoaurate(I) Anion, a Radical, and Cobalt(II) Ion Incorporating Gold···Gold and Hydrogen Bonding Interactions
Inorganic Chemistry2004Vol. 43(15), pp. 4552–4554
Citations Over TimeTop 10% of 2004 papers
Hui‐Bo Zhou, Shuping Wang, Wen Dong, Zhan‐Quan Liu, Qing‐Lun Wang, Dai‐Zheng Liao, Zong‐Hui Jiang, Shi‐Ping Yan, Peng Cheng
Abstract
A novel complex, [[CoAu2(CN)4(NITpPy)2(H2O)2]]n, 1, containing the cobalt(II) ion, dicyanoaurate(I) anion, and nitronyl nitroxide radical building blocks, has been prepared and structurally characterized by single-crystal X-ray analysis. The structure of complex 1 illustrates that aurophilicity and hydrogen bonding interactions increase dimensionality, generating a 2-D interdigitating system. The spectroscopic and magnetic properties have been investigated.
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