Chloro and Hydroxo Forms of a Boron(III) Subtriazaporphyrin Macrocycle
Inorganic Chemistry2006Vol. 45(16), pp. 6148–6151
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Jay R. Stork, Jeffrey J. Brewer, Takamitsu Fukuda, Jeffrey P. Fitzgerald, G.T. Yee, Alexander Y. Nazarenko, Nagao Kobayashi, W.S. Durfee
Abstract
cis-3,4-Dicyano-3-hexene undergoes cyclotrimerization with BCl3 to form the new subtriazaporphyrin chloro[hexaethylsubtriazaporphyrinato]boron(III). The hydroxo derivative of this macrocycle has also been made, and the X-ray crystal structure of the hydroxy form was determined. Electronic absorption and magnetic circular dichroism spectra of the hydroxo monomer species were interpreted using time-dependent density functional theory calculations.
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