Synthesis, Structure, and Luminescent Property of a Heterometallic Metal−Organic Framework Constructed from Rod-Shaped Secondary Building Blocks
Citations Over TimeTop 10% of 2005 papers
Abstract
A new heterometallic MOF compound, [ZnNa(m-BDC)2].NH2(CH3)2 (MOF-CJ2), has been solvothermally synthesized and characterized by single-crystal X-ray diffraction, X-ray powder diffraction, ICP, TGA, IR, and photoluminescence spectroscopy analyses. It crystallizes in monoclinic space group C2/c (No. 15) with a=13.277(6) A, b=14.323(7) A, c=11.328(6) A, and beta=111.73(2) degrees. Its framework is constructed from M-O-C (M=Na and Zn) rods composed of alternating six-coordinated Na(I) centers and four-coordinated Zn(II) centers. These rods are linked by m-BDC links to form primitive cubic (pcu) type rod packing. This framework exemplifies the first open-framework heterometallic MOF structure based on the assembly of infinite rod building units.
Related Papers
- → Axial thermal expansion of ZrO2and HfO2in the range room temperature to 1400°C(1969)212 cited
- → The structural transition of Gd2O3nanoparticles induced by high pressure(2007)31 cited
- → Structural and vibrational properties of phase-pure monoclinic NdLuO3 interlanthanides synthesized from nanostructured precursors(2016)5 cited
- → On the polymorphism of orthotelluric acid, H6TeO6(1968)10 cited
- → Investigation of Monoclinic Content on Clinically Retrieved Zirconia Heads(2005)2 cited