H2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers
Inorganic Chemistry2006Vol. 45(6), pp. 2397–2399
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Jorge A. R. Navarro, E. Barea, Juan M. Salas, Norberto Masciocchi, Simona Galli, Angelo Sironi, Conchi O. Ania, J.B. Parra
Abstract
H2, N2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2]n type, with M = Pd(II) or Cu(II) and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.
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