Mononitrosyl Iron Complexes Supported by Sterically Hindered Carboxylate Ligands
Inorganic Chemistry2006Vol. 45(20), pp. 8006–8008
Citations Over TimeTop 23% of 2006 papers
Abstract
Complexes that feature a single NO bound to Fe, as postulated in various carboxylate-rich metalloproteins, were prepared by mixing Fe(II) salts, NO, and the sterically encumbered 2,6-dimesitylbenzoate (Mes2ArCO2-). Among the compounds isolated are the potentially useful heterobimetallic synthon Tl(mu-Mes2ArCO2)3Fe(NO) and a novel cubane Fe4(Mes2ArCO2)4(NO)4(mu3-OH)4 that forms in the presence of added H2O and features syn-[FeNO]2 units.
Related Papers
- → SF5-Synthons: Pathways to Organic Derivatives of SF6(2005)31 cited
- → Cu(II)-Catalyzed [3 + 1 + 1 + 1] Cyclization of 1,3-Diketones and 2-Naphthols Using N,N-Dimethylethanolamine as a Dual Carbon Synthon for the Synthesis of 2H-Chromenes(2023)11 cited
- → Supramolecular Synthons: Will Giant Rigid Superspheres Do?(2016)16 cited
- → Comparison of pyridyl and pyridyl N-oxide groups as acceptor in hydrogen bonding with carboxylic acid(2014)14 cited
- → Mathematical Model of Synthon Reactions(1989)1 cited