Monohelical Iron(II) and Zinc(II) Complexes of a (1R,2R)-Cyclohexyl Salen Ligand with Benz[a]anthryl Sidearms
Inorganic Chemistry2006Vol. 45(25), pp. 10034–10036
Citations Over TimeTop 14% of 2006 papers
Abstract
An enantiomerically pure C2-symmetric salen ligand with benz[a]anthracene siderams produces M helical complexes (FeII and ZnII) in solution. Interconversion to produce a 1:1 mixture of helical conformers in the solid state is possible, despite overlapped sidearms.
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