Rationally Designed Micropores within a Metal−Organic Framework for Selective Sorption of Gas Molecules
Inorganic Chemistry2007Vol. 46(4), pp. 1233–1236
Citations Over TimeTop 1% of 2007 papers
Abstract
A microporous metal-organic framework, MOF, Cu(FMA)(4,4'-Bpe)0.5 (3a, FMA = fumarate; 4,4'-Bpe = 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) was rationally designed from a primitive cubic net whose pores are tuned by double framework interpenetration. With pore cavities of about 3.6 A, which are interconnected by pore windows of 2.0 x 3.2 A, 3a shows highly selective sorption behaviors of gas molecules.
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