Layered Heterometallic Iodoplumbate Containing a Novel Pb3Cu6I16 Net: Structure and Optical Properties
Inorganic Chemistry2006Vol. 45(26), pp. 10437–10439
Citations Over TimeTop 10% of 2006 papers
Michael C. Burns, M.A. Tershansy, Joseph M. Ellsworth, Z.M. Khaliq, L. Peterson, Mark D. Smith, Hans‐Conrad zur Loye
Abstract
A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3][Pb3Cu6I16].C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.
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