A Novel Asymmetric Hydroarsination Reaction Promoted by a Chiral Organopalladium Complex
Inorganic Chemistry2007Vol. 46(11), pp. 4733–4736
Citations Over TimeTop 11% of 2007 papers
Maricar L. Bungabong, Kien Wee Tan, Yongxin Li, S. Selvaratnam, Krishna Gopal Dongol, Pak‐Hing Leung
Abstract
The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.
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