Crystallographic Evidence of a Base-Free Uranium(IV) Terminal Oxo Species
Inorganic Chemistry2010Vol. 49(17), pp. 7620–7622
Citations Over TimeTop 10% of 2010 papers
Abstract
The uranium(IV) terminal oxo species Tp*(2)U(O) has been synthesized by oxygen-atom transfer from pyridine-N-oxide to Tp*(2)U(2,2'-bipyridine), a trivalent uranium species with a monoanionic bipyridine ligand. Full characterization of the oxo species using (1)H NMR and IR spectroscopies, X-ray crystallography, and computational studies was performed.
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