Surface Activation of Electrocatalysis at Oxide Electrodes. Concerted Electron−Proton Transfer
Inorganic Chemistry2011Vol. 50(6), pp. 2076–2078
Citations Over TimeTop 16% of 2011 papers
Abstract
Dramatic rate enhancements are observed for the oxidation of phenols, including tyrosine, at indium-tin oxide electrodes modified by the addition of the electron-transfer relays [M(II)(bpy)(2)(4,4'-(HO)(2)P(O)CH(2))(2)bpy)](2+) (M = Ru, Os) with clear evidence for the importance of proton-coupled electron transfer and concerted electron-proton transfer.
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