Formation of a Uranium Trithiocarbonate Complex via the Nucleophilic Addition of a Sulfide-Bridged Uranium Complex to CS2
Inorganic Chemistry2011Vol. 51(2), pp. 781–783
Citations Over TimeTop 10% of 2011 papers
Abstract
The uranium(IV)/uranium(IV) μ-sulfide complex [{(((Ad)ArO)(3)N)U}(2)(μ-S)] reacts with CS(2) to form the trithiocarbonate-bridged complex [{(((Ad)ArO)(3)N)U}(2)(μ-κ(2):κ(2)-CS(3))]. The trithiocarbonate complex can alternatively be formed in low yields from low-valent [(((Ad)ArO)(3)N)U(DME)] through the reductive cleavage of CS(2).
Related Papers
- → Isotopic Fractionation of Uranium in Sandstone(1963)144 cited
- → Kinetics of nucleophilic attack on coordinated organic moieties(1988)22 cited
- → Transition Metal‐Catalyzed Cycloisomerizations of Allenes(2004)12 cited
- → Reactions of Co‐Ordinated Carbonyl Compounds with Nucleophiles(1995)
- Experimental Study on the Relationship between Uranium(VI) and Total Uranium in Uranium Ores and Uranium-bearing Rocks(2010)