Improved Hydrogen Release from Ammonia–Borane with ZIF-8
Inorganic Chemistry2012Vol. 51(5), pp. 2728–2730
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Rui‐Qin Zhong, Ruqiang Zou, Tessui Nakagawa, Michael T. Janicke, Troy A. Semelsberger, Anthony K. Burrell, Rico E. Del Sesto
Abstract
The promotion for hydrogen release from ammonia-borane (AB) was observed in the presence of ZIF-8. Even at concentrations of ZIF-8 as low as 0.25 mol %, a reduction of the onset temperature for dehydrogenation accompanies an increase in both the rate and amount of hydrogen released from AB.
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