Porous Double-Walled Metal Triazolate Framework Based upon a Bifunctional Ligand and a Pentanuclear Zinc Cluster Exhibiting Selective CO2 Uptake
Inorganic Chemistry2012Vol. 51(8), pp. 4423–4425
Citations Over TimeTop 10% of 2012 papers
Wen‐Yang Gao, Wuming Yan, Rong Cai, Le Meng, Andrea Salas, Xi-Sen Wang, Łukasz Wojtas, Xiaodong Shi, Shengqian Ma
Abstract
The self-assembly of a custom-designed bifunctional ligand featuring both 1,2,3-triazolate and carboxylate donor groups with a pentanuclear zinc cluster generated in situ affords a double-walled metal triazolate framework (MTAF) material, MTAF-1 (Zn(5)(μ(3)-O)(2)(C(9)N(3)H(5)O(2))(5)(H(+))(4)(H(2)O)(17)(C(3)H(7)NO)(10)), which exhibits a surface area of 2300 m(2)/g and demonstrates interesting selective CO(2) uptake performances.
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