Synthesis of a High-Valent, Four-Coordinate Manganese Cubane Cluster with a Pendant Mn Atom: Photosystem II-Inspired Manganese–Nitrogen Clusters
Inorganic Chemistry2012Vol. 51(7), pp. 3950–3952
Citations Over TimeTop 23% of 2012 papers
Abstract
High-valent, four-coordinate manganese imido- and nitrido-bridged heterodicubane clusters have been prepared and characterized by single-crystal X-ray diffraction and spectroscopic techniques. The title compound, a corner-nitride-fused dicubane with the chemical formula [Mn(5)Li(3)(μ(6)-N)(N)(μ(3)-N(t)Bu)(6)(μ-N(t)Bu)(3)(N(t)Bu)] (1), has been prepared as an adduct with a nearly isostructural tetramanganese cluster with one Mn atom replaced by Li. An important feature of the reported chemistry is the formation of nitride from tert-butylamide, indicative of N-C bond cleavage facilitated by manganese.
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