[W(bipy)(CN)6]−: A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First CuIILnIIIWV Trinuclear Complexes
Inorganic Chemistry2012Vol. 51(9), pp. 4906–4908
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Maria‐Gabriela Alexandru, Diana Visinescu, Augustin M. Mădălan, Francesc Lloret, Miguel Julve, Marius Andruh
Abstract
The first 3d-4f-5d heterotrimetallic complexes using [W(V)(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.
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