Cobalt Polyoxometalates as Heterogeneous Water Oxidation Catalysts
Inorganic Chemistry2013Vol. 52(9), pp. 4753–4755
Citations Over TimeTop 10% of 2013 papers
Joaquín Soriano‐López, Sara Goberna‐Ferrón, Laura Vigara, Jorge J. Carbó, Josep M. Poblet, José Ramón Galán‐Mascarós
Abstract
An insoluble salt of the water oxidation catalyst [Co9(H2O)6(OH)3(HPO4)2(PW9O34)3](16-) (Co9) has been used to modify amorphous carbon paste electrodes. The catalytic activity of this polyoxometalate is maintained in the solid state. Good catalytic rates are reached at reasonable overpotentials. As a heterogeneous catalyst, Co9 shows a remarkable long-term stability in turnover conditions. The oxygen evolution rate remains constant for hours without the appearance of any sign of fatigue or decomposition in a large pH range, including acidic conditions, where metal oxides are unstable.
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