Dy(III) Single-Ion Magnet Showing Extreme Sensitivity to (De)hydration
Inorganic Chemistry2013Vol. 52(15), pp. 8342–8348
Citations Over TimeTop 10% of 2013 papers
Min Ren, Dawid Pinkowicz, Minyoung Yoon, Kimoon Kim, Li‐Min Zheng, Brian K. Breedlove, Masahiro Yamashita
Abstract
A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.
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