C–H Activation of 2,4,6-Triphenylphosphinine: Synthesis and Characterization of the First Homoleptic Phosphinine–Iridium(III) Complex fac-[Ir(C^P)3]
Inorganic Chemistry2013Vol. 52(19), pp. 10738–10740
Citations Over TimeTop 24% of 2013 papers
L.E.E. Broeckx, W. Delaunay, Camille Latouche, Martin Lutz, Abdou Boucekkine, Muriel Hissler, Christian Müller
Abstract
Access to homoleptic phosphinine-based coordination compounds of d(6) metals has so far remained elusive. We report here on the preparation and full characterization of the first homoleptic phosphinine-iridium(III) complex, obtained by C-H activation of 2,4,6-triphenylphosphinine with [Ir(acac)3]. This result opens up new perspectives for the implementation of such aromatic heterocycles in more applied research fields.
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