Activation of a High-Valent Manganese–Oxo Complex by a Nonmetallic Lewis Acid
Inorganic Chemistry2014Vol. 53(12), pp. 5893–5895
Citations Over TimeTop 10% of 2014 papers
Abstract
The reaction of a manganese(V)-oxo porphyrinoid complex with the Lewis acid B(C6F5)3 leads to reversible stabilization of the valence tautomer Mn(IV)(O)(π-radical cation). The latter complex, in combination with B(C6F5)3, reacts with ArO-H substrates via formal hydrogen-atom transfer and exhibits dramatically increased reaction rates over the Mn(V)(O) starting material.
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