A Three-Dimensional Microporous Metal–Metalloporphyrin Framework
Inorganic Chemistry2014Vol. 54(1), pp. 200–204
Citations Over TimeTop 10% of 2014 papers
Zhiyong Guo, Dan Yan, Hailong Wang, Daniel Tesfagaber, Xinle Li, Yu‐Sheng Chen, Wenyu Huang, Banglin Chen
Abstract
A new porphyrin-based microporous MOF, {Mn(II)0.5[Mn(II)4Cl(Mn(III)Cl-ttzpp)2(H2O)4]}·(DEF)20·(CH3OH)18·(H2O)12 (UTSA-57), has been constructed from {5,10,15,20-tetrakis[4-(2,3,4,5-tetrazolyl)phenyl]porphyrinato} manganese(III) chloride as the metalloligand. The MOF adopts the rare scu topology with one-dimensional square nanotube-like channels of about 20 Å. UTSA-57a exhibits permanent porosity and displays moderately high performance for C2H2/CH4 separation at room temperature.
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