A Criterion for the Anisotropy Barrier in Single-Molecule Magnets
Inorganic Chemistry2007Vol. 46(24), pp. 10035–10037
Citations Over TimeTop 10% of 2007 papers
Abstract
A criterion for the height of the anisotropy barrier Delta=|D|S2 in single-molecule magnets, and therefore the blocking temperature TB proportional to Delta, is presented. In particular, it is found that the anisotropy barrier does not increase with S as S2 but as S0. Consequences concerning the strategies to enhance Delta or TB, respectively, are discussed.
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