A New Dinuclear Ruthenium Complex as an Efficient Water Oxidation Catalyst
Citations Over TimeTop 10% of 2009 papers
Abstract
A dinuclear ruthenium complex, which acts as a molecular catalyst for water oxidation, has been synthesized and characterized. The electronic and electrochemical properties were studied by UV-vis spectroscopy and cyclic voltammetry. The oxidation potentials of the complex are significantly lowered by introducing a negatively charged carboxylate ligand, in comparison with those of the reported complexes that have neutral ligands. The catalytic activity of the complex toward water oxidation using Ce(NH(4))(2)(NO(3))(6) as a chemical oxidant was investigated by means of an oxygen electrode and mass spectrometry. The turnover number of this catalyst with Ce(IV) as the chemical oxidant was found to be ca. 1700. The mass spectroscopic analysis of the isotopomer distribution in oxygen evolved from (18)O-labeled water indicates that O atoms in the evolved oxygen originate from water.
Related Papers
- → Extractive Separation and Spectrophotometric Determination of Traces of Ruthenium from Mixtures Containing Excess Platinum Group Metals(2009)7 cited
- → Ligand control of metal oxidation states. Synthesis, characterization and cyclic voltammetric studies of a group of ruthenium phenolates(1996)18 cited
- THE FEATURES OF PROTEIN BINDING BY RUTHENIUM COMPLEXES: DOCKING, FORCE FIELD AND QM/MM STUDIES(2013)
- → Phosphorogenic and spontaneous formation of tris(bipyridine)ruthenium in peptide scaffolds(2019)1 cited
- → ANALYSIS BY THE RFES METHOD OF CATALYTIC SYSTEMS BASED ON RUTHENIUM(2023)