Ligand-Dependent Ultrasonic-Assistant Self-Assemblies and Photophysical Properties of Lanthanide Nicotinic/Isonicotinic Complexes
Citations Over TimeTop 10% of 2009 papers
Abstract
Two structural series, including two isomorphous homodinuclear complexes Ln2(H2O)4(C6NO2H4)6 (Ln = Tb (1) and Er (2)) and four isostructural one-dimensional (1-D) chain-like assemblies [Ln(H2O)4(C6NO2H4)2]n·nCl (Ln = Sm (3), Eu (4), Tb (5), and Dy (6)), have been rationally prepared through a facile ultrasonic synthesis and have been characterized by X-ray diffraction and photophysical measurements. Both complexes, 1 and 2, feature a homodinuclear structure, based on two 8-fold coordination lanthanide atoms bridged by four nicotinic acid ligands. Complexes 3−6 are characterized by a 1-D polycationic chain-like structure, containing eight-coordinated lanthanide ions and bridging isonicotinic acid ligands. The 1-D polycationic chains and the isolated chloride anions are interconnected via hydrogen bonds and π-π interactions to form a three-dimensional supramolecular network. The effect of nicotinic/isonicotinic acid ligands on the structures and the photoluminescence properties, as well as the relationship between the photoluminescence properties and the structures, was investigated based on IR, UV−vis absorption spectra, low temperature phosphorescent spectra, excitation, and emission spectra. The fluorescence quantum yields of complexes 1 and 2 were determined to be 44% and 21%, respectively.
Related Papers
- → Structure, resolution and chiroptical analysis of stable lanthanide complexes of a pyridylphenylphosphinate triazacyclononane ligand(2011)43 cited
- → Lanthanide-Based Coordination Polymers With 1,4-Carboxyphenylboronic Ligand: Multiemissive Compounds for Multisensitive Luminescent Thermometric Probes(2018)49 cited
- → Insights into isostructural and non-isostructural crystals of esters of oleanolic acid and its 11-oxo derivatives(2022)4 cited
- → Lanthanide contraction effects on the structures, thermostabilities, and CO2 adsorption and separation behaviors of isostructural lanthanide–organic frameworks(2015)22 cited
- → Three Isostructural 4‐Sulfophthalate‐Based Lanthanide Complexes: Syntheses, Crystal Structures, and Luminescent Properties(2015)6 cited