A Heterobimetallic Gallyl Complex Containing an Unsupported Ga−Y Bond
Inorganic Chemistry2009Vol. 48(8), pp. 3520–3522
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Stephen T. Liddle, David P. Mills, Benedict M. Gardner, Jonathan McMaster, Cameron Jones, W.D. Woodul
Abstract
The synthesis and characterization of the first unsupported Ga-Y bond in [Y{Ga(NArCH)(2)}{C(PPh(2)NSiMe(3))(2)}(THF)(2)] (Ar = 2,6-diisopropylphenyl) is described; structural and computational analyses are consistent with a highly polarized covalent Ga-Y bond.
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