Second-Harmonic Generation and Crystal Structure of the Diamond-like Semiconductors Li2CdGeS4 and Li2CdSnS4
Citations Over TimeTop 10% of 2009 papers
Abstract
The semiconductors Li(2)CdGeS(4) and Li(2)CdSnS(4), which are of interest for their nonlinear optical properties, were synthesized using high-temperature solid-state and polychalcogenide flux syntheses. Both compounds were found to crystallize in Pmn2(1), with R1 (for all data) = 1.93% and 1.86% for Li(2)CdGeS(4) and Li(2)CdSnS(4), respectively. The structures of both compounds are diamond-like with the tetrahedra pointing in the same direction along the c axis. The alignment of the tetrahedra results in the structure lacking an inversion center, a prerequisite for second-harmonic generation (SHG). A modified Kurtz nonlinear optical powder technique was used to determine the SHG responses of both compounds. Li(2)CdGeS(4) displayed a type I phase-matchable response of approximately 70x alpha-quartz, while Li(2)CdSnS(4) displayed a type I non-phase-matchable response of approximately 100x alpha-quartz. Diffuse-reflectance spectroscopy was used to determine band gaps of 3.10 and 3.26 eV for Li(2)CdGeS(4) and Li(2)CdSnS(4), respectively.
Related Papers
- → Growth, structural, optical, thermal, dielectric and second harmonic generation properties of 2-methylimidazolium malonate (2MIM) nonlinear optical single crystals(2019)8 cited
- → 657, a method for estimating tetrahedral bond angles(2001)11 cited
- → Volume Of A Tetrahedron Revisited(2014)7 cited
- → Arrangement of Central Points on the Faces of a Tetrahedron(2021)
- → GEOMETRY OF THE TETRAHEDRON AND COMPUTATION OF THE FACE ANGLES OF A TETRAHEDRON WITH THE HELP OF CLANGUAGE(2020)