Catalytic Water Oxidation by Single-Site Ruthenium Catalysts
Inorganic Chemistry2010Vol. 49(4), pp. 1277–1279
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Javier J. Concepcion, Jonah W. Jurss, Michael R. Norris, Zuofeng Chen, Joseph L. Templeton, Thomas J. Meyer
Abstract
A series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.
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