Extremely Efficient Alkane Oxidation by a New Catalytic Reagent H2O2/Os3(CO)12/Pyridine
Inorganic Chemistry2009Vol. 48(22), pp. 10480–10482
Citations Over TimeTop 10% of 2009 papers
Abstract
Triosmium dodecacarbonyl catalyzes a very efficient oxidation of alkanes by H(2)O(2) in MeCN to afford alkyl hydroperoxides (primary products) as well as alcohols and ketones (aldehydes) at 60 degrees C if pyridine is added in a low concentration. Turnover numbers attain 60,000, and turnover frequencies are up to 24,000 h(-1).
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