Facile Route to Nitrides: Transformation from Single Element to Binary and Ternary Nitrides at Moderate Temperature through a New Modified Solid-State Metathesis
Inorganic Chemistry2009Vol. 48(22), pp. 10519–10527
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Bo Song, Xiaolong Chen, Jiecai Han, Jikang Jian, Wanyan Wang, Hongbo Zuo, Xinghong Zhang, Songhe Meng
Abstract
In this article, we report a new modified solid-state metathesis pathway to synthesize nitrides using Li(3)N as a nitrification reagent to transform single element to nitrides. In this process, not only binary (including mono- and multinitrides) but also ternary nitrides can be approached by varying the molar ratio of Li(3)N to a single element. A possible two-step reaction mechanism for Li(3)N and single elements was proposed. This study provides a promising route to meet the increasing demand in energy savings and environmental protection for materials synthesis.
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