A Bivanadyl Capped, Highly Reduced Keggin Polyanion, [PMoV6MoVI6O40(VIVO)2]5-
Inorganic Chemistry1996Vol. 35(8), pp. 2403–2405
Citations Over TimeTop 10% of 1996 papers
Abstract
A bicapped, highly reduced vanadylpolymolybdophosphate Keggin complex [(C2H5)3NH]5[PMoV6MoVI6O40(VIVO)2], (TEA) 1, has been prepared hydrothermally and characterized by single-crystal X-ray diffraction, IR, UV/visible, cyclic voltammetry, elemental analysis, redox titration, and 51V and 31P NMR on its degradation products. The kinetics of decomposition of 1 in aqueous solution under both aerobic and anaerobic conditions is complex.
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