Structure and Reactivity of a Dinuclear Cobalt(III) Complex with a Bridging Phosphate Monoester
Inorganic Chemistry1996Vol. 35(26), pp. 7472–7473
Citations Over TimeTop 10% of 1996 papers
Abstract
The phosphate monoester in 2-H is hydrolyzed an unprecedented 1011 times more rapidly than the corresponding unbound phosphate. Clean conversion of the bidentate monoester (2-H) to the tridentate inorganic phosphate (3), together with the crystal structure of an analog of 2-H, provides detailed mechanistic insight into the hydrolysis reaction.
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