Vanadium Oxide Clusters as Building Blocks for the Synthesis of Metal Oxide Surfaces and Framework Materials: Synthesis and X-ray Crystal Structure of [H6Mn3VIV15VV4O46(H2O)12]·30H2O
Inorganic Chemistry1999Vol. 38(2), pp. 212–213
Citations Over TimeTop 10% of 1999 papers
Abstract
A novel mixed-metal oxide solid [H6Mn3VIV15VV4O46(H2O)12]·30H2O (1) has been synthesized and characterized. The structure of the mixed-valence compound consists of three-dimensional arrays of “spheres” of {V19O46}, each one linked by six μ2-{Mn(H2O)4} bridges to six neighboring {V19O46} units, generating a complex 3-D framework. The structure contains cavities occupied by readily removable lattice water.
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