Redox-Tunable Valence Tautomerism in a Cobalt Schiff Base Complex
Inorganic Chemistry2000Vol. 39(3), pp. 617–619
Citations Over TimeTop 10% of 2000 papers
Abstract
A new switching molecular array that interconverts reversibly either by thermal means (valence tautomerism) or by a reversible oxidation process has been established. Such an array is based on the rich electrochemical behavior of the cobalt Schiff base complex 2. The Schiff base ligand can exist in different oxidation forms that interconvert reversibly by means of redox processes and that can be used to obtain stable coordination complexes.
Related Papers
- → Identification, classification and relative stability of tautomers in the cambridge structural database(2010)68 cited
- → Tautobase: An Open Tautomer Database(2020)41 cited
- → Direct demonstration of tautomeric nature of 4‐bromo‐3(5)‐methylpyrazoles(2022)4 cited
- → The tautomerism of 6-hydroxy-, 6-amino- and 6-acylamino-7-azaindolines(1966)19 cited
- → Studies on the Tautomerism of 2-Anilinopyridine and Related Heterocycles. II. 2-Anilino-5-nitropyridine and 2-Anilinopyrimidine(1980)9 cited