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Cobalt phthalocyanine encapsulated in Y zeolite: a physicochemical study

The Journal of Physical Chemistry1993Vol. 97(49), pp. 12819–12827

Citations Over TimeTop 13% of 1993 papers

Edgardo Paez-Mozo, Nyole Gabriunas, Fabio Lucaccioni, Dwight D. Acosta, P. Patrono, A. La Ginestra, Patricio Ruíz, Bernard Delmon

Abstract

Cobalt phthalocyanine was synthesized within the cavities of Y zeolites and was characterized in all the steps of the synthesis and purification procedures by elemental analysis, Fourier transform infrared spectroscopy, UV-visible spectroscopy, X-ray photoelectron spectroscopy, surface analysis, thermogravimetric analysis, differential thermal analysis, X-ray diffraction, and conventional transmission and high-resolution electron microscopy. Besides the cobalt phthalocyanine (12% in weight), other nitrogen-containing compounds (2% in weight) are associated to the acidic sites of the zeolite and/or axially coordinated to the cobalt complex.

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