Very high chemoselective, regioselective, and E-stereoselective 1,3-chirality transfer involving reaction of acyclic (E)- and (Z)-.gamma.-mesyloxy .alpha.,.beta.-enoates and organocyanocopper-trifluoroborane reagents. Efficient synthetic routes to functionalized chiral .alpha.-alkyl (E)-.beta.,.gamma.-enoates and (E)-allylic alcohols with high optical purity

Citations Over TimeTop 10% of 1989 papers

Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTVery high chemoselective, regioselective, and E-stereoselective 1,3-chirality transfer involving reaction of acyclic (E)- and (Z)-.gamma.-mesyloxy .alpha.,.beta.-enoates and organocyanocopper-trifluoroborane reagents. Efficient synthetic routes to functionalized chiral .alpha.-alkyl (E)-.beta.,.gamma.-enoates and (E)-allylic alcohols with high optical purityToshiro Ibuka, Miwa Tanaka, Shinji Nishii, and Yoshinori YamamotoCite this: J. Am. Chem. Soc. 1989, 111, 13, 4864–4872Publication Date (Print):June 1, 1989Publication History Published online1 May 2002Published inissue 1 June 1989https://pubs.acs.org/doi/10.1021/ja00195a045https://doi.org/10.1021/ja00195a045research-articleACS PublicationsRequest reuse permissionsArticle Views545Altmetric-Citations66LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

Related Papers

• → Vinylogous carbinolamine tumor inhibitors. 20. Comparison of the chemical reactivities and antineoplastic activities of .alpha.,.beta.-, .alpha.,.beta.'-, .beta.,.beta.'- and .alpha.,.alpha.'-bis[[[(2-propylamino)carbonyl]oxy]methyl] substituted pyrroles(1986)9 cited
• → ChemInform Abstract: REACTION OF ETHYL ALPHA,BETA‐UNSATURATED ALPHA‐ OR BETA‐NITROCARBOXYLATES WITH SODIUM AZIDE(1974)
• Regiospecific syntheses of modified steroid hormones. V. 6 Beta-fluoro-7 alpha-hydroxy-17 beta-oestradiol, 7 alpha-fluoro-6 alpha-hydroxy-17 beta-oestradiol, and 7 alpha-fluoro-17 beta-oestradiol.(1973)
• Reduction of .BETA.-alkylthio .ALPHA.,.BETA.-unsaturated ketones [R1COCH=C(R2)SR3] with LiAlH4 or NaBH4: Conversion to .ALPHA.,.BETA.-unsaturated ketones (R1CH=CHCOR2).(1979)