Geometric equivalents of enantiomers in studies of the stereochemical course of substitution at carbon. Electronic effects in nucleophilic addition to carbonyl groups and to carbocations. Virtual proof of the existence of .sigma. participation by unstrained carbon-carbon bonds

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Abstract

ADVERTISEMENT RETURN TO ISSUEPREVArticleNEXTGeometric equivalents of enantiomers in studies of the stereochemical course of substitution at carbon. Electronic effects in nucleophilic addition to carbonyl groups and to carbocations. Virtual proof of the existence of .sigma. participation by unstrained carbon-carbon bondsC. K. Cheung, L. T. Tseng, M. H. Lin, S. Srivastava, and W. J. Le NobleCite this: J. Am. Chem. Soc. 1986, 108, 7, 1598–1605Publication Date (Print):April 1, 1986Publication History Published online1 May 2002Published inissue 1 April 1986https://doi.org/10.1021/ja00267a034RIGHTS & PERMISSIONSArticle Views601Altmetric-Citations99LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated. Share Add toView InAdd Full Text with ReferenceAdd Description ExportRISCitationCitation and abstractCitation and referencesMore Options Share onFacebookTwitterWechatLinked InReddit PDF (1 MB) Get e-AlertscloseSupporting Info (1)»Supporting Information Supporting Information Get e-Alerts

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