Photoinduced Ferrimagnetic Systems in Prussian Blue Analogues CIxCo4[Fe(CN)6]y (CI = Alkali Cation). 4. Characterization of the Ferrimagnetism of the Photoinduced Metastable State in Rb1.8Co4[Fe(CN)6]3.3·13H2O by K Edges X-ray Magnetic Circular Dichroism
Journal of the American Chemical Society2001Vol. 123(50), pp. 12544–12546
Citations Over TimeTop 10% of 2001 papers
Guillaume Champion, Virginie Escax, Christophe Moulin, Anne Bleuzen, Françoise Villain, F. Baudelet, E. Dartyge, Michel Verdaguer
Abstract
In Part 2 of this work, the electronic and local structure of the photoinduced metastable magnetic state of the Prussian blue analogue Rb1.8Co4[Fe(CN)6]3.3-13H2O were characterized. To determine directly the relative orientation of the magnetic moments of Co(II) and Fe(III) ions in the metastable state, and the nature of the exchange interaction between them, we performed X-ray magnetic circular dichroism (XMCD) experiments at the cobalt and iron K edges. We present the first direct experimental evidence of the antiferromagnetic interaction between the cobalt and the iron ions, leading to the ferrimagnetism of the photoinduced metastable state.
Related Papers
- → X-ray Magnetic Circular Dichroism for Quantitative Element-Resolved Magnetic Microscopy(2004)17 cited
- → Investigating Orbital Magnetic Moments in Spinel-Type MnV2O4 Using X-ray Magnetic Circular Dichroism(2015)16 cited
- → Generic features of a photo-induced magnetic structure, exhibited by the Rb0.52Co[Fe(CN)6]0.84, 2.31H2O Prussian Blue analogue(2001)23 cited
- → X-ray Magnetic Circular Dichroism of Ferromagnetic Semiconductor Ge1−xMnxTe(2005)2 cited
- → Cu K edge X-ray magnetic circular dichroism of amorphous Gd68Cu32(2006)