Reactions of Iodinated Vinylidene Complexes Generated from 1-Iodo-1-alkynes and W(CO)5(thf)
Journal of the American Chemical Society2002Vol. 124(4), pp. 518–519
Citations Over TimeTop 10% of 2002 papers
Abstract
We have succeeded in generating iodinated tungsten vinylidene complexes from 1-iodo-1-alkynes and W(CO)5(thf), and have employed these complexes for two types of synthetically useful reactions, that is, 6pi-electrocyclization for o-(iodoethynyl)styrenes and endo-selective cyclization for omega-iodoacetylenic silyl enol ethers.
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