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The Mechanism of Aminations of Halobenzenes1
Journal of the American Chemical Society1956Vol. 78(3), pp. 601–611
Citations Over TimeTop 10% of 1956 papers
Abstract
An elimination-addition mechanism, probably involving a "benzyne" intermediate, has been established for the rearrangements which often occur in the conversion of non-activated aryl halides to arylamines with metallic amides. The evidence for the "benzyne" intermediate was obtained through ^(14)C-tracer studies of rearrangements with halobenzenes and experiments designed to determine the role of the hydrogen atom located ortho to the displaced halogen atom.
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