Large Photocurrent Generation of Gold Electrodes Modified with [60]Fullerene-Linked Oligothiophenes Bearing a Tripodal Rigid Anchor
Journal of the American Chemical Society2002Vol. 124(4), pp. 532–533
Citations Over TimeTop 1% of 2002 papers
Daigo Hirayama, Kazuo Takimiya, Yoshio Aso, Tetsuo Otsubo, Taku Hasobe, Hiroko Yamada, Hiroshi Imahori, Shunichi Fukuzumi, Yoshiteru Sakata
Abstract
[60]Fullerene-linked quarter- and octithiophenes bearing a tripodal rigid anchor have been synthesized as components of highly efficient SAM-based photovoltaic cells. It has been demonstrated that the tripodal anchor plays an important role in preparing a well-organized SAM on a gold electrode, leading to marked enhancement of the photocurrent generation as compared to the reference system with a one-armed anchor.
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