Highly Enantioselective Alkynylzinc Addition to Aromatic Aldehydes Catalyzed by Self-Assembled Titanium Catalysts
Journal of the American Chemical Society2002Vol. 124(43), pp. 12636–12637
Citations Over TimeTop 10% of 2002 papers
Abstract
A highly enantioselective catalyst generated by a combination of BINOL and another ligand with Ti(OiPr)4 was found to be highly effective for the alkynylzinc addition to aromatic aldehydes with enantioselectivities as high as >99%.
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